If you check on your profile, you will probably see that each single photo appear as “approved” but on your statistics the number is lower.
This is because the info attached to every photo are related to the basic requirements (size and resolution) while the final approval is checking the photo itself, quality and contents. Normally to me it was taking 24 to 48 hours, to have my photos approved.
After that, you will be able to switch ON the available for hire switch